Switchable Surface Hydrophobicity–Hydrophilicity of a Metal–Organic Framework

Rodríguez-Hermida, S., Tsang, M. Y., Vignatti, C., Stylianou, K. C., Guillerm, V., Pérez-Carvajal, J., Teixidor, F., Viñas, C., Choquesillo-Lazarte, D., Verdugo-Escamilla, C., Peral, I., Juanhuix, J., Verdaguer, A., Imaz, I., Maspoch, D. and Giner Planas, J. (2016), Angew. Chem. Int. Ed.. doi:10.1002/anie.201609295

Materials with surfaces that can be switched from high/superhydrophobicity to superhydrophilicity are useful for myriad applications. Herein, we report a metal–organic framework (MOF) assembled from ZnII ions, 1,4-benzenedicarboxylate, and a hydrophobic carborane-based linker. The MOF crystal-surface can be switched between hydrophobic and superhydrophilic through a chemical treatment to remove some of the building blocks.

Sustainable energy conversion & storage systems

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